Indonesian Journal on Geoscience
Vol 8, No 4 (2013)

Characteristics and Origin of Sedimentary-Related Manganese Layers in Timor Island, Indonesia

Idrus, Arifudin ( Department of Geological Engineering, Gadjah Mada University, Yogyakarta )
Ati, E. M. ( Department of Geological Engineering, Gadjah Mada University, Yogyakarta )
Harijoko, A. ( Department of Geological Engineering, Gadjah Mada University, Yogyakarta )
Meyer, F. M. ( Department of Mineralogy & Economic Geology, RWTH Aachen University, Germany Templergraben 55, 52056 Aachen )



Article Info

Publish Date
03 Jul 2014

Abstract

DOI: 10.17014/ijog.v8i4.169Sedimentary-related manganese layers have been discovered in South Central Timor Regency, Timor Island, Indonesia, which is tectonically active and being uplifted due to north-trending tectonic collision between Timor Island arc and Australian continental crust. The manganese layers of 2 to 10 cm-wide interbed with deep sea sedimentary rocks including reddish - reddish brown claystone, radiolarian chert, slate, marl as well as white and pinkish calcilutite of Nakfunu Formations. Stratigraphically, the rock formations are underlain by Bobonaro Formation. Two types of manganese ores found comprise manganese layers and manganese nodule. The manganese layers strongly deformed, lenticular, and segmented, are composed of manganite [MnO(OH)], groutite [MnO(OH)], pyrolusite (MnO2), lithioporite (Al,Li) MnO2(OH)2, and hollandite [Ba (Mn4+, Mn2+)8O16] associated with gangue minerals including calcite, quartz, limonite [FeO(OH)], hematite (Fe2O3), and barite (BaSO4). Whilst the nodule type is only composed of manganite and less limonite. Geochemically, the manganese layers have grade of 63 - 72 wt.% MnO, whereas the nodule one has grade of 63 - 69 wt.% MnO. Generally, iron in Mn ore is very low ranging from 0.2 to 1.54 wt.% Fe2O3, averaged 0.76 wt.%. Hence, Fe/Mn ratio which is very low (0.003 - 0.069), typically indicates a sedimentary origin, which is also supported by petrologic and petrographic data showing layering structure of manganite and lithioporite crystal/grain. Trace element geochemistry indicates that manganese ore was precipitated in a reduction condition. Rare earth element (REE) analysis of manganese ore shows an enrichment of cerium (Ce) suggesting that the ore is basically originated in a marine environment. The manganese nodule is interpreted to be formed by chemical concretion process of unsoluble metals (i.e. mangan, iron) in seawater (hydrogenous) and precipitated on deep sea bottom. On the other hand, the manganese layer is a detrital diagenetic deposit formed by Mn remobilization in seawater column, precipitated and sedimented on the deep sea bottom. Manganese layers have probably been influenced by ‘hydrothermal process’ of mud-volcano activities, proven by the presence of quartz and barite veinlets cutting the Mn layers, manganite recrystallization to be pyrolusite along veinlets cutting manganite and lithioporite layers, and the presence of pyrite and sulphur associated with Mn layers. Field data also exhibit that the significant manganese layers are mostly found around mud volcanoes. The closely spatial and genetic relationships between manganese layers and mud-volcanoes might also be an important guide for the exploration of Mn deposit in the region.

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Journal Info

Abbrev

IJOG

Publisher

Subject

Earth & Planetary Sciences

Description

The spirit to improve the journal to be more credible is increasing, and in 2012 it invited earth scientists in East and Southeast Asia as well as some western countries to join the journal for the editor positions in the Indonesia Journal of Geology. This is also to realize our present goal to ...