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All Journal JURNAL KIMIA SAINS DAN APLIKASI Alchemy Jurnal Penelitian Kimia ALCHEMY Jurnal Penelitian Kimia Indonesian Journal of Chemistry
Dian Maruto Widjonarko
Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta 57126 Central Java
Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Engineering Environmental Science Materials Science & Nanotechnology

Published : 7 Documents
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PREPARATION AND CHARACTERIZATION OF THE MONOMETAL CATALYST Mo/ USY Nugrahaningtyas, Khoirina Dwi; Trisunaryanti, Wega; Triyono, Triyono; Nuryono, Nuryono; Widjonarko, Dian Maruto; Mulyani, Mulyani
Alchemy Jurnal Penelitian Kimia Vol 8, No 1 (2012)
Publisher : Alchemy Jurnal Penelitian Kimia

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Abstract

This research deals with preparing and characterizing the metal based-catalyst of Mo supported on Ultra Stable Y-zeolite (USY) and, is aimed to ascertain the best produced catalyst for hydrotreatment reaction in standpoint of its capabilities on removing the unwanted-heteroatom compounds.Procedure of catalyst treatment was preparation, activation and characterization. Monometal catalyst Mo/USY was prepared under variation concentrations of salt metal precursor (concentrations), i.e 2, 6, 10 and 14% wt. The activation steps were carried out by calcination, oxidation, and reduction. Characterization of catalysts were determined by data of XRD, AAS, acidity, surface area and its porosity. The result shows that these catalysts have several good characters that supporting their usefulness in hydrotreatment-catalytic reaction. In addition, catalyst Mo10/USY performs many ideal criteria as the best functional catalyst.
ALUMINASI FELDSPAR PADA TANAH ABU VULKANIK (TAV) DENGAN LARUTAN ALUMINIUM KLORIDA HEKSAHIDRAT Heraldy, Eddy; Widjonarko, Dian Maruto; Saputro, Sigit Wiwiet
Alchemy Jurnal Penelitian Kimia Vol 3, No 2 (2004)
Publisher : Alchemy Jurnal Penelitian Kimia

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Abstract

Telah dilakukan aluminasi feldspar pada Tanah Abu Vulkanik (TAV) gunung Lawu dengan menggunakan larutan aluminium klorida heksahidrat 0,1 M. Aluminasi dilakukan pada suhu 30, 50, 70 dan 90oC masing-masing selama 6 jam. Perlakuan kalsinasi terhadap sampel sebelum dan sesudah aluminasi dilakukan selama 6 jam pada 550oC.Hasil penelitian menunjukkan bahwa proses aluminasi feldspar pada suhu 30, 50, 70 dan 90oC tidak cukup berpengaruh. Difraktogram menunjukkan bahwa struktur sampel pada suhu aluminasi 30oC dan 90oC masih tetap di pertahankan sebagai mineral feldspar dengan kristalinnitas yang semakin meningkat.
KAJIAN AKTIVASI H2SO4 TERHADAP PROSES PEMILARAN Al2O3 PADA LEMPUNG ALAM Nugrahaningtyas, Khoirina Dwi; Widjonarko, Dian Maruto; Daryani, Daryani; Haryanti, Yunita
ALCHEMY Jurnal Penelitian Kimia Vol 12, No 2 (2016): Alchemy Jurnal Penelitian Kimia
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.12.2.1312.190-203

Abstract

Telah dilakukan penelitian tentang lempung alam (bentonit) yang diaktivasi dengan berbagai variasi konsentrasi H2SO4, dan dengan proses interkalasi menggunakan larutan Al2O3.H2O. Tujuan dari penelitian ini adalah untuk menentukan konsentrasi optimum untuk aktivasi lempung, berdasarkan karakter persentase montmorillonite dan keasaman total. Hal ini juga didukung oleh karakterisasi setelah proses interkalasi, yaitu karakter luas permukaan spesifik, volume pori total, radius pori rata-rata dan kandungan aluminium. Analisis persentase-Montmorilonit dilakukan dengan menggunakan difraksi sinar X; keasaman total ditentukan secara gravimetri; luas permukaan spesifik, volume pori total, dan jari-jari pori rata-rata diukur dengan Surface Area Analyzer NOVA dan kandungan aluminium ditentukan oleh Analisis Aktivasi Neutron.Hasil penelitian menunjukkan bahwa aktivasi optimum pada konsentrasi H2SO4 1,5 M mempunyai persentase montmorillonite optimum (91.335%) dan nilai keasaman meningkat 193.955% dari nilai keasaman bentonit alam. Karakter fisik dan kimia setelah interkalasi juga menunjukkan bahwa terjadi peningkatan kadar aluminium (57,540%), luas permukaan spesifik (150,586%), volume total pori (73,236%) dan keasaman Total (203,504%) dari bentonit alam. Rerata jejari pori mengalami penurunan 10,274% setelah aktivasi dan penurunan 30,868% setelah proses interkalasi.
THE PARAFFIN CRACKING REACTION WITH NiMo/ACTIVE NATURAL ZEOLITE CATALYST: THE EFFECT TEMPERATURE ON CATALYTIC ACTIVITYTHE PARAFFIN CRACKING REACTION WITH NiMo/ACTIVE NATURAL ZEOLITE CATALYST: THE EFFECT TEMPERATURE ON CATALYTIC ACTIVITY Nugrahaningtyas, Khoirina Dwi; Cahyono, Eko; Widjonarko, Dian Maruto
ALCHEMY Jurnal Penelitian Kimia Vol 11, No 2 (2015): Alchemy Jurnal Penelitian Kimia
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.11.2.712.111-126

Abstract

This research deals with the study of the paraffin cracking reaction with termal reaction, active natural zeolite (ZAA) and NiMo / active natural zeolite (ZAA) catalyst. Temperature variation was done in order to study the optimum temperature of paraffin cracking reactions. Paraffin cracking reaction carried out at temperatures of 200 - 400 °C and a hydrogen flow rate of 30 mL / min. Cracking products obtained, and then analyzed by gas chromatography (GC) and gas chromatography-mass spectrometry(GCMS). Catalyst activity (%) was defined as the amount of lighter fractions/the amount of feed (paraffin) (%). The results showed that the catalyst NiMo/ZAA has the highest activity (31.33 %) at the cracking reaction temperature of 300 ºC
Phosphonate Modified Silica for Adsorption of Co(II), Ni(II), Cu(II), and Zn(II) Widjonarko, Dian Maruto; Jumina, Jumina; Kartini, Indriana; Nuryono, Nuryono
Indonesian Journal of Chemistry Vol 14, No 2 (2014)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.21251

Abstract

A new phosphonate modified silica (PMS) has been investigated for adsorption of Co(II), Ni(II), Cu(II), and Zn(II) in aqueous solution. The adsorbent was modified of silica by immobilizing aminoethyl dihydrogen phosphate (AEPH2) on 1,4-dibromobutane grafted silica. The physicochemical of the adsorbent was investigated using Fourier Transform Infra-red (FTIR) spectroscopy, X-ray Fluorescence (XRF), and N2 gas adsorption/desorption. The adsorption study was carried out in a batch system by mixing solution of metal ions at various pHs, contact times, and initial metal ion concentrations. The unadsorbed metals were determined by Flame Atomic Absorption Spectrophotometry (FAAS). Result of characterization showed that PMS has been successfully prepared. The product contained 45.99% (w/w) silica and 1.33% (w/w) phosphorous with surface area, pore volume, and pore size of 115.3 m2g-1; 0.7578 mLg-1; and 131.44 Å, respectively. Adsorption of metal ions on PMS occurred quite fast, less than 30 min. Modification of phosphonate on silica increased the adsorption capability, up to 8 times higher than that of unmodified silica, depending on metal ion type and pH solution. The capacity order of the metals adsorption was Cu(II)>Co(II)>Ni(II)>Zn(II). Based on the adsorption characteristic, the adsorbent is promising to be applied as a material for solid phase extraction of transition metal ions.
PREPARATION AND CHARACTERIZATION THE NON-SULFIDED METAL CATALYST: Ni/USY and NiMo/USY Nugrahaningtyas, Khoirina Dwi; Trisunaryanti, Wega; Triyono, Triyono; Nuryono, Nuryono; Widjonarko, Dian Maruto; Yusnani, Ari; Mulyani, Mulyani
Indonesian Journal of Chemistry Vol 9, No 2 (2009)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.21526

Abstract

The two-new catalysts had been prepared by using the impregnation method according to Nugrahaningtyas [6] and Li [4]. One catalyst is of Nickel (Ni), supported on Ultra Stable Zeolite Y (USY), whereas the other one is NiMo supported on same supporting agent. These new catalysts are expected to be more effective when applied on the hydrotreatment reaction in standpoint of its capabilities on removing the unwanted-heteroatom. Characterization those two types of catalysts then carried out by using the criteria of acidity, porosity and, metal content. The result shows that these non-sulfide catalysts have several good characters that supporting their usefulness in hydrotreatment-catalytic reaction. In addition, catalyst NiMo/USY - 1 performs many ideal criteria as the best functional catalyst.   Keywords: Non-sulfided Catalyst, hydro-treating, preparation, characterization
Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Al Ichsan, Gesyth Mutiara Hikhmah; Nugrahaningtiyas, Khoirina Dwi; Widjonarko, Dian Maruto; Rahmawati, Fitria; Lestari, Witri Wahyu
Jurnal Kimia Sains dan Aplikasi Vol 22, No 1 (2019): volume 22 Issue 1 Year 2019
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jksa.22.1.7-10

Abstract

Conversion of wood waste into bio-oil with low temperature pyrolysis method has been successfully carried out using tubular transport reactors. Pyrolysis carried out at temperatures of 250-300°C without using N2 gas. Bio-oil purified by a fractionation distillation method to remove water and light fraction compounds. The materials obtained from different types of wood waste, namely: Randu wood (Ceiba pentandra), Sengon wood (Paraserianthes falcataria), Coconut wood (Cocos nucifera), Bangkirei wood (Shorea laevis Ridl), Kruing wood (Dipterocarpus) and Meranti wood (Shorea leprosula). Bio-oil products are analyzed for their properties and characteristics, namely the nature of density, acidity, high heat value (HHV), and elements contained in bio-oil such as carbon, nitrogen and sulfur content based on SNI procedures, while bio-oil chemical compositions are investigated using Gas Chromatography Mass Spectroscopy (GC-MS). The maximum yield of bio-oil products occurs at 300°C by 40%. Bio-oil purification by fractional distillation method can produce purity of 16-31% wt. The characterization results of the chemical content of bio-oil showed that bio-oil of methyl formate, 2,6-dimetoxy phenol, 1,2,3 trimethoxy benzene, levoglucosan, 2,4-hexadienedioic acid and 1,2- benzenediol.
Co-Authors Al Ichsan, Gesyth Mutiara Hikhmah Ari Yusnani Daryani Daryani Eddy Heraldy Eko Cahyono, Eko Fitria Rahmawati Haryanti, Yunita Indriana Kartini Jumina Jumina Khoirina Dwi Nugrahaningtyas Lestari, Witri Wahyu Mulyani Mulyani Nugrahaningtiyas, Khoirina Dwi Nuryono Nuryono Sigit Wiwiet Saputro, Sigit Wiwiet Triyono Triyono Wega Trisunaryanti