Iip Izul Falah
Departement of Chemistry Faculty of Sciences and Mathematics Universitas Gadjah Mada Yogyakarta

Published : 12 Documents
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Analisis pengaruh penambahan ion H+ pada sintesis material mesopori Al-MCM-41 menjadi H-MCM-41 Tengker, Soenandar Milian Tompunu; Falah, Iip Izul
Jurnal Kimia Fullerene Vol 3 No 1 (2018): Fullerene Journal of Chemistry
Publisher : Chemistry Department State University of Manado

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (500.999 KB)

Abstract

Sintesis material mesopori Al-MCM-41 dibuat menjadi H-MCM-41 telah dilakukan dengan cara mencampur sebanyak 5 gram Al-MCM-41 hasil sintesis ke dalam 100 ml larutan NH4Cl 0,5 M, kemudian disaring dan dicuci serta dikeringkan dalam oven pada suhu 80 oC selama 24 jam. Situs asam yang terkandung pada material mesopori H-MCM-41 adalah situs asam Brønsted (B) dan situs asam Lewis (L). Material mesopori H-MCM-41 hasil sintesis menunjukkan bentuk morfologi berupa pori heksagonal seperti sarang lebah (honeycomb). Hal ini juga memperjelas bahwa CTAB sebagai bahan pengarah struktur pori telah berhasil membentuk pori fasa heksagonal dari material mesopori H-MCM-41 hasil sintesis. Ukuran diameter pori dari material mesopori H-MCM-41 hasil sintesis adalah 2,88 Å diukur menggunakan mistar ukur berdasarkan skala gambar hasil analisis menggunakan TEM.
ESTIMATION OF PROTEIN CONCENTRATION IN FOOD BY TOTAL NITROGEN AND AMINO ACID ANALYSES ., Sumarno; Noegrohati, Sri; ., Narsito; Falah, Iip Izul
INDONESIAN JOURNAL OF PHARMACY Vol 13 No 1, 2002
Publisher : Faculty of Pharmacy Universitas Gadjah Mada, Yogyakarta, Skip Utara, 55281, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (194.079 KB) | DOI: 10.14499/indonesianjpharm0iss0pp34-43

Abstract

Since protein is the principal constituent of biological organs, a continuous supply is needed in food for growth and repair. Protein quality in food is determined by its assortment of amino acids, whether it is essentially needed or not. The aim of this study is to develop an accurate and precise simple method of protein estimation for food and feed. The validity of simple protein estimation by multiplying the N-total concentration with a constant factor: of 6.25, should be clarified. Protein could be estimated more specifically by summing up the determined amino acids. In this study, the amino acids of some substantially high protein food were analysed by HPLC-ninhydrin, HPLC-o-phthalaldehyde, and HPLC-dansyl techniques, by gas chromatograph after derivation with TFA-butanol, and by formol titration. Method based on HPLC-ninhydrin techniques shows significant correlation (r=0-9992) with its amino acids content and N-total content. The protein as amino acids - N-total conversion factor obtained was 6.95 for N-total content less than 15.5%, and 8.59 for N-total content higher than 15.5%.Key words: food, protein and analytical methods
Gasoline Production from Coconut Oil Using The Ni-MCM-41 and Co/Ni-MCM-41 Catalyst Badriyah, Lailatul; Falah, Iip Izul
JKPK (Jurnal Kimia dan Pendidikan Kimia) Vol 2, No 1 (2017): JKPK (Jurnal Kimia dan Pendidikan Kimia)
Publisher : Program Studi Pendidikan Kimia FKIP Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (451.221 KB) | DOI: 10.20961/jkpk.v2i1.8516

Abstract

Gasoline have been produced from coconut oil using MCM-41, NiMCM-41, and Co/NiMCM-41 catalyst. The acidity of catalyst was analysed by Fourier Transformation Infra-Red Spectroscopy (FTIR). The yields of cracking product were analysed by Gas Chromatography-Mass Spectroscopy (GC-MS). The catalyst of Co/NiMCM-41 has the highest acidity than MCM-41 and NiMCM-41. It is caused by the effect of adding d orbital from Co and Ni. This cracking process is batch system, and the catalyst pellets were made at the temperature of 400 ºC. The highest gasoline product was obtained using the Co/NiMCM-41 catalyst with 89.53 % w/w yield. The major liquid product from the cracking process using MCM-41, NiMCM-41, dan Co/NiMCM-41 catalysts were estimated as 1-octena, octane, nonane; 1-octene, 1-nonene, nonane; 1-octene, octane, nonane, respectively. 
Determination of Antioxidant Activity and Phenolic Compounds of Methanolic Extract of Java Plum (Syzygium cumini Linn. (Skeel) Seed Rohadi, Rohadi; Santoso, Umar; Raharjo, Sri; Falah, Iip Izul
Indonesian Food and Nutrition Progress Vol 14, No 1 (2017)
Publisher : Indonesian Association of Food Technologists

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ifnp.24279

Abstract

Methanolic extract of Java Plum (Syzygium cumini L. (Skeel) seed (MEJS) is potential source of natural antioxidant. As indicated by several in vitro measurements, the extract had strong DPPH (1,1 diphenyl, 2–picryl hydrazyl) and ABTS (2,2-azinobis, 3-ethylbenzothiazoline-6-sulphonate) radical scavenging activity, strong Ferric Reducing Antioxidant Power (FRAP) and moderate inhibition activity of linoleic acid oxidation. This study aimed to determine antioxidant activity and phenolic compound of Java Plum seed (Syzygium cumini L. (Skeel) methanolic extract fractions. Phenolics compound identification using Thin Layer Chromatography (TLC) showed that all fractions (polar, semi polar and hydrolyzed semi polar fraction) contained Gallic acid, Tannic acid and flavonol’s Rutin. HPLC-DAD analysis showed that its polar fraction contained 25 ppm flavonol’s Quercetine and 55181 ppm flavonol’s (+)- Catechin, ethyl acetate fraction contained 54 ppm flavonol’s Rutin and 528 ppm (+)- Catechine, while hydrolyzed ethyl acetate fraction contained 404 ppm Rutin and 28692 ppm (+)- Catechine.
Wormhole-Like Mesoporous Carbons from Gelatine as Multistep Infiltration Effect Ulfa, Maria; Trisunaryanti, Wega; Falah, Iip Izul; Kartini, Indriana
Indonesian Journal of Chemistry Vol 16, No 3 (2016)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (227.776 KB) | DOI: 10.22146/ijc.21137

Abstract

Wormhole-like mesoporous carbon from gelatine (WMCG) with two different pore diameters have been synthesized by adopting a modified infiltration treatment. The infiltration effect on the morphology was investigated. The results show that the WMCG sample was obtained after dehydration, pyrolysis and silica removal process. The pore diameters WMCG are 15.2 and 4.8 nm with specific surface areas of 280 m2/g, total pore volumes of 0.5 cm3/g and the thermal stability up to 1400 °C. The bimodal pore of WMCG obtained as the high step of infiltration level effect.
Reversible Second Order Kinetics of Sorption-Desorption of Cr(VI) Ion on Activated Carbon from Palm Empty Fruit Bunches Falah, Iip Izul; Ruliatima, Ruliatima; Triyono, Triyono
Indonesian Journal of Chemistry Vol 15, No 3 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (325.388 KB) | DOI: 10.22146/ijc.21198

Abstract

Activated carbon (AC) from palm empty fruit bunches has been prepared, and this material was then used to adsorb Cr(VI) from a solution. Characterization of the AC was conducted by detection of its functional groups, determination of total volatile compounds (VC) content and its iodine number. Study on sorption-desorption kinetics was conducted by comparing results of evaluations of several models with proposed reversible second order model using the data produced in this work. Results of the works showed that the AC had similar characters compared with the AC produced by previous researchers. Application of the kinetics models on sorption Cr(VI) onto the AC showed that nearly all of the models gave a good linearity. However, only the proposed model had a good relation with Langmuir isotherm, with respectively sorption (ks) and desorption (kd) constants were 5.75 x 10-4 L.mg‑1.min-1 and 2.20 x 10-3 min-1; maximum sorption capacity, qm = 20.00 mg.g-1; and equilibrium constant, K from kinetics experiment (0.261 L.mg-1) was comparable with the result from the isotherm experiment (0.269 L.mg-1). Hence, using this model, kinetics and Langmuir parameters can probably be determined from a single kinetics data experiment.
Preparation of Nickel/Active Carboncatalyst and its Utilization for Benzene Hydrogenation Septiawati, Enggelena; Falah, Iip Izul; Alim, RHA. Sahirul
Indonesian Journal of Chemistry Vol 1, No 2 (2001)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.21951

Abstract

The research on the preparation of nickel catalyst impregnated on active carbon by two methods has been carried out. The impregnation of Ni metal was done using nickel(II) chloride as a precursor. The impregnated of Ni metal on samples in A method was made in varying of percentage i.e., 0.5, 1.0 and 2.0% (w/w) as the weight proportion of Ni to active carbon and NiCl2.6H20. The concentration of Ni that would be impregnated on samples in B method was made close to Ni content of samples in A method determined by atomic adsorption spectrometry. Preparation of nickel/active carbon catalyst with A method was done with dipping the active carbon in the nickel(II) chloride solution followed by filtering and then drying at 110 °C for 4 hours, and then calcination by flowing nitrogen and reduction by hydrogen, each at 400 °C at 4 hours. The treatments made on samples in A method was also done on samples in B method, the only difference was evaporating all of precursor solution after dipping active carbon in that precursor solution was done in B method. The characterization includes: iodium adsorption test, determination of nickel content by means of atomic adsorption spectrometry, and acidity by adsorption of ammonia methods. Test of catalyst activity was done by means of hydrogenation of benzene to cyclohexane at 150, 200 and 250 °C, the pressure of 1 atm and the flow rate of hydrogen 6 mL/minute. The products were analyzed by gas chromatographic method. The results show that A method produced a catalyst with relatively low nickel content. However the acidity and ability to convert benzene to cyclohexane were relatively high and it increased as increasing the content of nickel. The temperature of the reaction was achieved at 250 °C which gave the yield on conversion of 25.3678%. The catalyst obtained by B method in the same condition of hydrogenation gave only smaller results.
Spectrophotometric Determination of the CuSO4 Soret Coefficient of a CuSO4-H2O Binary Solutions System Rohman, Ijang; Sasmita, Djaka; Falah, Iip Izul
Indonesian Journal of Chemistry Vol 1, No 2 (2001)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.21946

Abstract

A spectrophotometric technique for the determination of the CuSO4 soret coefficient of a CuSO4-water binary solutions system is described. A short column of solutions is placed between horizontal metal plates that are held at different temperatures. The subsequent changes in composition due to thermal diffusion are followed by monitoring changes of transmittance near the end of the solutions column. In water, CuSO4 diffuses to the warm compartment of column. The soret coefficient of CuSO4 0.0254 molal in water agrees with the appropriate theory, i.e. 17.60x10-3 °C-1 on the average.
OXIDATION KINETICS AND QUANTIFICATION METHOD OF CHOLESTEROL USING CHOLESTEROL OXIDASE ENZYME CATALYST Falah, Iip Izul; Ritmaleni, Ritmaleni; Yahya, M. Utoro
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (328.973 KB) | DOI: 10.22146/ijc.21486

Abstract

In view of health, cholesterol is believed as one of many sources can raise several diseases. Hence, both of research in quantification and developing simple, rapid and accurate analysis method of cholesterol in a sample is very important. Aim of this research was to investigate cholesterol oxidation kinetics and its quantification method based on oxidation of cholesterol and formation complex compound of hexathiocyanato ferat(III), {Fe(SCN)6}-3. The kinetics analysis and quantification, involved cholesterol oxidation in 0.1 M and pH 7.0 phosphate buffer solution to produce cholest-4-en-3-one and hydrogen peroxide, in the presence of cholesterol oxidase enzyme. The formed hydrogen peroxide was used to oxidize iron(II) ion, which was reacted furthermore with thiocyanate ion to raise the red-brown complex compound. Results of the study showed that the complex was stable at 10-120 min since the reaction was started, with maximum wavelength of 530-540 nm. While the kinetics analysis gave first order oxidation reaction with a reaction rate constant, kapp = 5.22 x 10-2 min-1. Based on this kinetics data, cholesterol analysis method could be developed i.e. by oxidizing cholesterol within 1.5 h using cholesterol oxidase as a catalyst, and then reacted with Fe2+, in a solution containing thiocyanate ion. Absorbencies of solutions of the complex compound, measured at wavelength of 535 nm, were linearly proportional to their cholesterol concentrations, in the range of 50-450 ppm.   Keywords: cholesterol, quantification, kinetics, hexathiocyanato ferat(III)
EXTRACTION, CLEAN-UP, AND HPLC DETECTION OF CARBARYL AND CARBOFURAN FROM CABBAGE (Brassica oleracea) Falah, Iip Izul
Indonesian Journal of Chemistry Vol 9, No 3 (2009)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (214.104 KB) | DOI: 10.22146/ijc.21514

Abstract

Carbaryl (1-naphthyl-N-methylcarbamate) and carbofuran (2,3-dihydro-2,2-dimethyl-7-benzofuranol-N-methylcarbamate) are very important N-methylcarbamate pesticides due to their high insecticide and nematocide effects, and widely used in vegetables plantations. The increasing use of carbamate pesticides poses a risk to human and environment. Thus, it is necessary to quantify their residue amount in food and vegetables to prevent harmful effect on animals, human and environment. This work was aimed to study of carbaryl and carbofuran analysis from fortified cabbage (Brassica oleracea) by liquid-liquid extraction, clean-up using SPE, followed by HPLC detection. Result of the work showed that detection of carbaryl using spectrophotometer detector at wavelength of 220 nm was better than at 230 and 280 nm, respectively. When the carbamates were extracted from cabbage using methanol, followed by liquid-liquid extraction using dichloromethane, cleaned-up with SPE-C18 and eluted by acetonitrile, the recovery was 96.8%. The detection by HPLC involved 4.6 x 25 mm, 5 µm C18 column, spectrophotometer detector at wavelength of 220 nm, and isocratic mobile phase at ratio of 35:65 of acetonitrile:aquabidest gave a good separation between co-extracted compounds and the carbamates.   Keywords: HPLC, carbaryl, carbofuran, extraction, clean-up